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A Comparison of Water Vapor Line Parameters for Modeling the Venus Deep Atmosphere

机译:金星深层建模水汽线参数比较   大气层

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摘要

The discovery of the near infrared windows into the Venus deep atmosphere hasenabled the use of remote sensing techniques to study the composition of theVenus atmosphere below the clouds. In particular, water vapor absorption linescan be observed in a number of the near-infrared windows allowing measurementof the H2O abundance at several different levels in the lower atmosphere.Accurate determination of the abundance requires a good database of spectralline parameters for the H2O absorption lines at the high temperatures (up to~700 K) encountered in the Venus deep atmosphere. This paper presents acomparison of a number of H2O line lists that have been, or that couldpotentially be used, to analyze Venus deep atmosphere water abundances andshows that there are substantial discrepancies between them. For example, theearly high-temperature list used by Meadows and Crisp (1996) had largesystematic errors in line intensities. When these are corrected for using themore recent high-temperature BT2 list of Barber et al. (2006) their value of45+/-10 ppm for the water vapor mixing ratio reduces to 27+/-6 ppm. The HITRANand GEISA lists used for most other studies of Venus are deficient in "hot"lines that become important in the Venus deep atmosphere and also show evidenceof systematic errors in line intensities, particularly for the 8000 to 9500cm-1 region that includes the 1.18 um window. Water vapor mixing ratios derivedfrom these lists may also be somewhat overestimated. The BT2 line list isrecommended as being the most complete and accurate current representation ofthe H2O spectrum at Venus temperatures.
机译:进入金星深层大气的近红外窗口的发现使得能够使用遥感技术研究云层下方金星大气的成分。特别是,可以在许多近红外窗口中观察到水蒸气吸收线,从而可以在较低的大气层中以几种不同的水平测量H2O的丰度。准确确定丰度需要在H2O吸收线的光谱线参数的良好数据库金星深层大气中遇到的高温(最高约700 K)。本文对已经或可能用于分析金星深层大气水丰度的许多H2O线清单进行了比较,并表明它们之间存在实质性差异。例如,Meadows and Crisp(1996)使用的早期高温清单在线强度上存在较大的系统误差。当使用最新的高温BT2 Barbar等人的清单进行校正时。 (2006年)他们的水蒸气混合比值的45 +/- 10 ppm降低到27 +/- 6 ppm。用于金星的其他大多数研究的HITRAN和GEISA列表缺少在金星深层大气中变得重要的“热”线,并且还显示了线强度的系统误差的证据,尤其是对于包括1.18 um的8000至9500cm-1区域窗口。从这些列表中得出的水蒸气混合比也可能被高估了。推荐BT2线路列表是金星温度下H2O谱的最完整,最准确的电流表示形式。

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    Bailey, Jeremy;

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  • 年度 2009
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